I have converted Win 10, on a GPT disk, to Win 10, on a MBR disk, a few times, while testing ArcaOS. My method should work okay, as long as the physical disk is not more than 2 TB.
Briefly:
First BACK UP WINDOWS. Having said that, the only backup program, that I know of, that actually works, is Acronis. Acronis does come in a couple of limited capability, free versions. One works, if you have a Seagate, Samsung, or some other brand (all owned by Seagate). The disk can be in an external enclosure, and doesn't need to be used for the backup. The other is from Western Digital (don't know much about that one). Google for Seagate Discwizard.
Before continuing, you may want to experiment with an old disk, if you have one. Using the disc wizard can be a bit confusing.
Next, use a stand alone DFSEE boot, to wipe the front end of the disk. Then use an OS/2 installer (preferably ArcaOS) to create ALL of the desired partitions (including windows). Do NOT, ever, allow any other disk utility (except DFSEE, running under OS/2) to mess with the partitions.
Now you can restore windows, and proceed to install OS/2 along side of it.