Well, I deleted the Qt6 directory, unzipped it a new (thanks for fixing the zip), it wanted avcode59 so I copied over the FFmpeg DLLs and it started up without the external vpx113 or dav1d6.dll and is trying to run an AV YouTube video right now, got to about 20 seconds and stalled.
Searching, I do have KOMH's dav1d.dll in @nixroot\usr\local\lib from installing VLC, no vpx113 and it is not being used as I just renamed it.
Searching the qt6-6.2.x\lib directory for vpx, it is found in Qt6WebEe.dll, 262,231K 07/11/23/9:32PM
Dooble once again crashed in the same spot, though YouTube is still displayed with the video hung.
CPU usage is low too. Hmm, it is the main page crashing, the video I opened is still showing in its own tab.
I'd suggest others trying it without single-process.
OK, system hung, luckily SeaMonkey remembered this post after the boot.